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Americium

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Americium, 95Am
Americium
Pronunciation/ˌæməˈrɪsiəm/ (listenⓘ) ​(AM-ə-RISS-ee-əm)
Appearancesilvery white
Mass number[243]
Americium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Eu
↑
Am
↓
(Uqe)
plutonium ← americium → curium
Atomic number (Z)95
Groupf-block groups (no number)
Periodperiod 7
Block  f-block
Electron configuration[Rn] 5f7 7s2
Electrons per shell2, 8, 18, 32, 25, 8, 2
Physical properties
Phase at STPsolid
Melting point1449 K ​(1176 °C, ​2149 °F)
Boiling point2880 K ​(2607 °C, ​4725 °F) (calculated)
Density (near r.t.)12 g/cm3
Heat of fusion14.39 kJ/mol
Molar heat capacity28[1] J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1239 1356
Atomic properties
Oxidation states+2, +3, +4, +5, +6, +7 (an amphoteric oxide)
ElectronegativityPauling scale: 1.3
Ionization energies
  • 1st: 578 kJ/mol
Atomic radiusempirical: 173 pm
Covalent radius180±6 pm
Color lines in a spectral range
Spectral lines of americium
Other properties
Natural occurrencesynthetic
Crystal structure ​double hexagonal close-packed (dhcp)
Double hexagonal close packed crystal structure for americium
Thermal conductivity10 W/(m⋅K)
Electrical resistivity0.69 µΩ⋅m[1]
Magnetic orderingparamagnetic
Molar magnetic susceptibility+1000.0×10−6 cm3/mol[2]
CAS Number7440-35-9
History
Namingafter the Americas
DiscoveryGlenn T. Seaborg, Ralph A. James, Leon O. Morgan, Albert Ghiorso (1944)
Isotopes of americium
Main isotopes[3] Decay
abun­dance half-life (t1/2) mode pro­duct
241Am synth 432.2 y α 237Np
SF –
242m1Am synth 141 y IT 242Am
α 238Np
SF –
243Am synth 7350 y α 239Np
SF –
 Category: Americium
| references
A small disc of americium metal as seen in a microscope. This object has americium-241

Americium is a transuranic, radioactive chemical element with the symbol Am and the atomic number 95. In chemistry, it is placed in a group of metal elements named the actinides. Americium does not exist in nature and has to be made by chemists

Americium is silver in color, and is made by bombarding a plutonium target with neutrons.

It was the fourth transuranic element to be discovered. It was named for the Americas, like europium was named for Europe.[4][5]

The longest half life of any type of americium is 7370 years.[6]

Americium in a smoke detector battery

Production of Americium

[change | change source]

Americium is a synthetic element, so it must be made by people and is not found in nature. Most americium is made as a byproduct of nuclear reactors, and can be separated out during nuclear reprocessing.

The two most stable isotopes of americium are 241Am and 243Am. They are made by beta decay of the same-weight plutonium isotopes, 241Pu and 243Pu, which are made from neutron capture in thermal reactors.

Most americium is 241Am. 241Pu has a 14 year half-life and large fission cross section, so decaying to americium is rare in active reactors. Most 241Am is found in spent nuclear fuel, where plutonium is more likely to decay than go through fission. 241Am is also a byproduct of nuclear weapons production, which needs to separate 241Pu from 239Pu to produce weapons-grade plutonium.

Americium is used in ionization-type smoke detectors. The level of radioactivity is not enough to cause cancer, and it cannot get through the smoke detector's plastic case, so it is safe to live in a place where smoke detectors with americium are used. This type of smoke detector is becoming obsolete, and is being replaced by optical smoke detectors, which have fewer false alarms and don't contain radioactive material.

References

[change | change source]
  1. 1 2 Muller, W.; Schenkel, R.; Schmidt, H. E.; Spirlet, J. C.; McElroy, D. L.; Hall, R. O. A.; Mortimer, M. J. (1978). "The electrical resistivity and specific heat of americium metal". Journal of Low Temperature Physics. 30 (5–6): 561. Bibcode:1978JLTP...30..561M. doi:10.1007/BF00116197.
  2. ↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  3. ↑ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  4. ↑ Kostecka, Keith (2008). "Americium – From Discovery to the Smoke Detector and Beyond" (PDF). Bull. Hist. Chem. 33 (2): 89–93. Archived from the original (PDF) on 2022-10-09.
  5. ↑ "C&En: It's Elemental: The Periodic Table - Americium".
  6. ↑ "Americium Video - The Periodic Table of Videos - University of Nottingham". www.periodicvideos.com. Retrieved 2022-04-19.